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91.
The removal of chemicals in solution by overland flow from agricultural land has the potential to be a significant source of chemical loss where chemicals are applied to the soil surface, as in zero tillage and surface‐mulched farming systems. Currently, we lack detailed understanding of the transfer mechanism between the soil solution and overland flow, particularly under field conditions. A model of solute transfer from soil solution to overland flow was developed. The model is based on the hypothesis that a solute is initially distributed uniformly throughout the soil pore space in a thin layer at the soil surface. A fundamental assumption of the model is that at the time runoff commences, any solute at the soil surface that could be transported into the soil with the infiltrating water will already have been convected away from the area of potential exchange. Solute remaining at the soil surface is therefore not subject to further infiltration and may be approximated as a layer of tracer on a plane impermeable surface. The model fitted experimental data very well in all but one trial. The model in its present form focuses on the exchange of solute between the soil solution and surface water after the commencement of runoff. Future model development requires the relationship between the mass transfer parameters of the model and the time to runoff to be defined. This would enable the model to be used for extrapolation beyond the specific experimental results of this study. The close agreement between experimental results and model simulations shows that the simple transfer equation proposed in this study has promise for estimating solute loss to surface runoff. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   
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Modelling the hydrology of North American Prairie watersheds is complicated because of the existence of numerous landscape depressions that vary in storage capacity. The Soil and Water Assessment Tool (SWAT) is a widely applied model for long‐term hydrological simulations in watersheds dominated by agricultural land uses. However, several studies show that the SWAT model has had limited success in handling prairie watersheds. In past works using SWAT, landscape depression storage heterogeneity has largely been neglected or lumped. In this study, a probability distributed model of depression storage is introduced into the SWAT model to better handle landscape storage heterogeneity. The work utilizes a probability density function to describe the spatial heterogeneity of the landscape depression storages that was developed from topographic characteristics. The integrated SWAT–PDLD model is tested using datasets for two prairie depression dominated watersheds in Canada: the Moose Jaw River watershed, Saskatchewan; and the Assiniboine River watershed, Saskatchewan. Simulation results were compared to observed streamflow using graphical and multiple statistical criterions. Representation of landscape depressions within SWAT using a probability distribution (SWAT–PDLD) provides improved estimations of streamflow for large prairie watersheds in comparison to results using a lumped, single storage approach. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
95.
The first measurement of atomic oxygen concentration in the upper atmosphere using the resonance absorption lamp method was made 23 January 1974 in a flight from the Churchill Research Range (58.4°N, 94.1°W, geographic) in northern Canada. Earlier difficulties with the data analysis have been resolved to a limited extent, and a concentration profile over the range 90–155 km is presented here. In the interim period, the same technique has been employed by a number of investigators, but the importance of the present data is that the atomic oxygen concentration was measured by three independent methods on the same flight, aeronomical and mass spectrometric methods being used as well as resonance absorption. The results are in good agreement when current aeronomical understanding is employed. Comparison is made with other measurements and it is concluded that the high degree of variability observed may well be real. A simple argument based on these data shows that O2(c1Σ) cannot be the sole source of O(1S) and O2(b1Σ) in the aurora.  相似文献   
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Daily, photometric, full-disk digital solar images have been taken at the San Fernando Observatory (SFO) at two resolutions and in several wavelengths for more than eleven years. We describe the standard data processing techniques used for these images, including: calibration, limb fitting, geometric correction, and production of a solar contrast map by limb-darkening removal. The resulting contrast maps have a photometric accuracy which is often a few tenths of a percent. We show that the geometric accuracy of our images, as measured by the reproducibility of disk and sunspot areas, is very high as well. The techniques described in this paper should be applicable to any instrument producing full-disk photometric images.  相似文献   
98.
The formation of the high‐pressure compositional equivalents of olivine and pyroxene has been well‐documented within and surrounding shock‐induced veins in chondritic meteorites, formed by crystallization from a liquid‐ or solid‐state phase transformation. Typically polycrystalline ringwoodite grains have a narrow range of compositions that overlap with those of their olivine precursors, whereas the formation of iron‐enriched ringwoodite has been documented from only a handful of meteorites. Here, we report backscattered electron images, quantitative wavelength‐dispersive spectrometry (WDS) analyses, qualitative WDS elemental X‐ray maps, and micro‐Raman spectra that reveal the presence of Fe‐rich ringwoodite (Fa44‐63) as fine‐grained (500 nm), polycrystalline rims on olivine (Fa24‐25) wall rock and as clasts engulfed by shock melt in a previously unstudied L5 chondrite, Dhofar 1970. Crystallization of majorite + magnesiowüstite in the vein interior and metastable mineral assemblages within 35 μm of the vein margin attest to rapid crystallization of a superheated shock melt (>2300 K) from 20─25 GPa to ambient pressure and temperature. The texture and composition of bright polycrystalline ringwoodite rims (Fa44‐63; MnO 0.01─0.08 wt%) surrounding dark polycrystalline olivine (Fa8‐14; MnO 0.56─0.65 wt%) implies a solid‐state transformation mechanism in which Fe was preferentially partitioned to ringwoodite. The spatial association between ringwoodite and shock melt suggests that the rapidly fluctuating thermal regimes experienced by chondritic minerals in contact with shock melt are necessary to both drive phase transformation but also to prevent back‐transformation.  相似文献   
99.
Stormwater along ephemeral arroyos and areal infiltration in nearby boreholes were studied in the Amargosa Desert Region of Southern Nevada, USA. Chemical composition of ephemeral stream runoff was measured at elevations below where areal infiltration generally occurs in arid environments using lysimeters designed for this study. Borehole cuttings from several wells were evaluated in terms of chloride migration. Analysis of the borehole data indicates that net areal infiltration has been insignificant for the past 10 000+ years. This is associated with an environment where chloride and other soluble salts accumulate in shallow sediments and potentially in runoff waters. Measured storm events during the 4‐year study period were small and localized but sufficient to produce surface runoff, at least near the lysimeters. Composition of storm runoff captured by the lysimeters was found to be a combination of the water chemistry types found in precipitation and from leaching tests of near‐surface sediments. All major cations and bicarbonate increased relative to chloride when precipitation interacted with sediments to form ephemeral stream runoff. The changes were consistent with calculated saturation indices. Despite the long‐term accumulation of chloride in soils and deep sediments caused by complete evapotranspiration of infiltrating precipitation, runoff waters were characterized by low chloride and total dissolved solids. This study presents a limitation of the chloride mass‐balance method, as chloride and water migration were disassociated from each other in the study area. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
100.
The littoral drift rose (LDR) concept is presented herein for improvement in understanding of longshore sediment transport and consequent shoreline processes in areas with smooth (gradually varying) offshore bathymetry extending over a coastal region where the deep water wave climate is reasonably uniform. The concept of the littoral drift rose (LDR) is presented and LDRs are shown to provide insight into coastal evolution and shoreline stability (or instability) for a given region having uniform wave climate. This paper reviews earlier documented applications and work using LDRs and provides an interpretation of earlier findings of shoreline stability using LDRs. Previously known but undocumented findings are also discussed herein which show that the wave climate and hence the LDR can be synthesized into an equivalent LDR developed from one wave component of given magnitude and direction. Practical applications using LDRs are presented, which show that the magnitude and direction of littoral drift throughout a region can be interpreted from limited measured, calculated, or observed data on littoral drift at two locations in the region.  相似文献   
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